Natural Gas Liquefication Process:
A
liquefied natural gas plant (LNG plant) is roughly divided into five processes:
1
pretreatment,
2 acid
gas Removal,
3 Dehydration,
4
liquefaction and
5 Heavy oil separations.
(1) In the pretreatment process,
undesired substances are removed from the gas taken from a gas field. Then the
gas is separated using a separator/slug catcher into oil and water which are
then weighed.
(2)Natural gas taken from a gas field
contains environmental pollutants like hydrogen sulfide (H2S) and
carbon dioxide (CO2). These impure substances are absorbed and
removed from natural gas with an amine absorber (acid gas removal or AGR). With
the use of a sulfur removal unit (SRU), sulfur is extracted from the hydrogen
sulfide in the removed pollutant.
(3)An adsorbent is used to remove water
from the natural gas from which impure substances have been removed so that ice
will not form during the subsequent liquefaction process.
(4)Traces of harmful mercury are removed
before liquefaction.
(5)The heavy compounds separation process
is the core of an LNG plant in which natural gas is cooled and liquefied to
–160°C or less using the principle of refrigeration. Because gas is cooled and
liquefied to an extremely-low temperature during the process, an enormous
amount of energy is consumed. How much this energy can be reduced is important,
so various ingenious processes have been proposed and commercialized.
Major
liquefaction processes are as follows:
1) C3-MR method: The C3-MR method is
currently the main method. Propane and mixed coolants (nitrogen, methane,
ethane and propane) are used as the coolant (APCI), and an improvement on this
method called the AP-X method is also used for large LNG plants.
2) AP-X method: As liquefaction trains
get larger, they approach a limit on the size of heat exchanger that can be
produced and transported. This process can increase LNG production capacity by
adding LNG sub-coolers with nitrogen coolant used according to the C3-MR
method, without increasing the size of the main heat exchanger (APCI).
3) Cascade method: This method
sequentially uses propane, ethylene and methane as the coolant (Phillips).
4) DMR method: This method uses two kinds
of mixed coolants (an ethane and propane mix and a nitrogen-methane, ethane and
propane mix) (Shell).
5) SMR method: This method is called the
PRICO process and uses only one kind of mixed coolant (Black & Veatch).
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